二苯甲酰甲烷
1,3-二苯基-1,3-丙二酮(英语:1,3-diphenyl-1,3-propanedione,常用名:二苯甲酰甲烷,英语:dibenzoylmethane,缩写DBM) 是一种芳香基间二酮,是乙酰丙酮(acac)的甲基上的氢被苯基取代的衍生物。
单词 | Dibenzoylmethane |
释义 |
Dibenzoylmethane
中文百科
二苯甲酰甲烷1,3-二苯基-1,3-丙二酮(英语:1,3-diphenyl-1,3-propanedione,常用名:二苯甲酰甲烷,英语:dibenzoylmethane,缩写DBM) 是一种芳香基间二酮,是乙酰丙酮(acac)的甲基上的氢被苯基取代的衍生物。
英语百科
Dibenzoylmethane 二苯甲酰甲烷1,3-Diphenyl-1,3-propanedione (dibenzoylmethane, DBM) is an aromatic 1,3-diketone derivative of acetylacetone (acac), where both methyl groups in acac have been substituted by phenyl groups. It is a white solid melting at 77−78 °C. Similar to acac, DBM exists in two tautomeric forms, with the keto-enol equilibrium of DBM shifting strongly towards the enol form, particularly in non-polar solvents such as benzene. This is the result of the stability of the intramolecular hydrogen bond in the cis-enol form which is further resonance-stabilized by conjugation with phenyl rings. Due to its high photostability, derivatives of DBM such as avobenzone, have found applications as sunscreen products. |
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