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单词 CT complex
释义

CT complex

中文百科

电荷转移配合物 Charge-transfer complex

(重定向自CT complex)

电荷转移配合物(charge-transfer complex, CT complex)是两个或两个分子以上或者一个大分子的不同部分的、有电荷转移作用的配合物。其中提供电子的一方叫做电子给体,接受电子的一方叫做电子受体。如SO2·I2是一个电荷转移配合物。

英语百科

Charge-transfer complex 电荷转移配合物

(重定向自CT complex)
Fig. 1 I2•PPh3 charge-transfer complexes in CH2Cl2. From left to right: (1) I2 dissolved in dichloromethane - no CT complex. (2) A few seconds after excess PPh3 was added - CT complex is forming. (3) One minute later after excess PPh3 was added, the CT complex [Ph3PI]+I− has been formed. (4) Immediately after excess I2 was added, which contains [Ph3PI]+[I3]−.[7]

A charge-transfer complex (CT complex) or electron-donor-acceptor complex is an association of two or more molecules, or of different parts of one large molecule, in which a fraction of electronic charge is transferred between the molecular entities. The resulting electrostatic attraction provides a stabilizing force for the molecular complex. The source molecule from which the charge is transferred is called the electron donor and the receiving species is called the electron acceptor.

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更新时间:2025/6/23 6:04:08