碗烯




心环烯(Corannulene),又名碗烯,是一种多环芳香烃,化学式C20H10,由一个环戊烷周围并五个苯环组成,它具有碗状的空间结构,可看做是富勒烯C60的一个片段。在−64℃时,碗状结构翻转的能垒是42.7kJ/mol(10.2 kcal/mol)。
单词 | Corannulene |
释义 |
Corannulene
中文百科
碗烯![]() ![]() ![]() ![]() 心环烯(Corannulene),又名碗烯,是一种多环芳香烃,化学式C20H10,由一个环戊烷周围并五个苯环组成,它具有碗状的空间结构,可看做是富勒烯C60的一个片段。在−64℃时,碗状结构翻转的能垒是42.7kJ/mol(10.2 kcal/mol)。
英语百科
Corannulene 碗烯![]() ![]() ![]() ![]() Corannulene is a polycyclic aromatic hydrocarbon with chemical formula C20H10. The molecule consists of a cyclopentane ring fused with 5 benzene rings, so another name for it is [5]circulene. It is of scientific interest because it is a geodesic polyarene and can be considered a fragment of buckminsterfullerene. Due to this connection and also its bowl shape, corannulene is also known as a buckybowl. Corannulene exhibits a bowl-to-bowl inversion with an inversion barrier of 10.2 kcal/mol (42.7 kJ/mol) at −64 °C. |
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