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单词 xanthogenate
释义

xanthogenate /'zænθədʒineit/

英汉-汉英词典
n. 黄原酸盐
词组 | 习惯用语
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  • pathogenesis n. 发病机理
  • hydrogenate vt. 使 ... 与氢化合
  • pathogenic adj. 引起疾病的
  • xanthogen n. 黄原
xanthogenate n. [有化] 黄原酸盐,[有化] 黄原酸酯

网络短语:
ethyl xanthogenate 黄原酸乙酯;乙黄药
sodium xanthogenate 乙基黄原酸钠;黄原酸钠;黄酸钠
potassium xanthogenate 黄原酸钾;黄酸钾;黄原酸钾英语
cellulose xanthogenate 纤维素黄原酸盐;黄原酸纤维素
Bisisopropyl xanthogenate 连二异丙基黄原酸酯
propyl xanthogenate 翻译;丙黄原酸盐
chitosan xanthogenate 壳聚糖黄原酸盐
xanthogenate derivatives 黄原酸衍生物
glycerol sodium xanthogenate 丙三醇黄原酸钠
中文百科

黄原酸酯 Xanthate

(重定向自Xanthogenate)
Cellulose xanthate (orange).
Structure of typical metal tris(ethylxanthate) complex.[6]
Formation of sodium cellulose xanthate starting from cellulose (top)

黄原酸酯(Xanthate)是黄原酸(ROC(=S)SH)形成的酯类,通式见右图,以特征的黄色而得名。用作选矿剂和RAFT法中活性自由基聚合反应的控制剂。

由二硫化碳与相应少一个碳的醇盐反应生成黄原酸盐,再用烷基化试剂处理便可得到黄原酸酯。黄原酸酯经Chugaev反应,在200°C热解生成烯烃,是通过醇消除制取烯烃的一种方法,不会发生重排。

英语百科

Xanthate 黄原酸酯

(重定向自Xanthogenate)
Cellulose xanthate (orange).
Structure of typical metal tris(ethylxanthate) complex.[6]
Formation of sodium cellulose xanthate starting from cellulose (top)

Xanthate usually refers to a salt with the formula ROCS2M (R = alkyl; M+ = Na, K). The name xanthates is derived from Greek ξανθός [ksantʰós], meaning “yellowish, golden”, and indeed most xanthate salts are yellow. They were discovered and named in 1823 by the Danish chemist William Christopher Zeise. These organosulfur compounds are important in two areas, the production of cellophane and related polymers from cellulose and secondly in mining for the extraction of certain ores. They are also versatile intermediates in organic synthesis. Xanthates also refer to esters of xanthic acid. These esters have the structure ROC(=S)SR'.

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更新时间:2025/6/20 3:55:06