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单词 Olefin metathesis
释义

Olefin metathesis

中文百科

烯烃复分解反应

烯烃复分解反应英语:Olefin metathesis)涉及金属催化剂存在下烯烃双键的重组,自发现以来便在医药和聚合物工业中有了广泛应用。相对于其他反应,该反应副产物及废物排放少,更加环保。

2005年的诺贝尔化学奖颁给了化学家伊夫·肖万、罗伯特·格拉布和理乍得·施罗克,以表彰他们在烯烃复分解反应研究和应用方面所做出的卓越贡献。

烯烃复分解反应由含镍、钨、钌和钼的过渡金属卡宾配合物催化,反应中烯烃双键断裂重组生成新的烯烃,通式如下:

英语百科

Olefin metathesis 烯烃复分解反应

Olefin metathesis is an organic reaction that entails the redistribution of fragments of alkenes (olefins) by the scission and regeneration of carbon-carbon double bonds. Catalysts for this reaction have evolved rapidly for the past few decades. Because of the relative simplicity of olefin metathesis, it often creates fewer undesired by-products and hazardous wastes than alternative organic reactions. For their elucidation of the reaction mechanism and their discovery of a variety of highly efficient and selective catalysts, Yves Chauvin, Robert H. Grubbs, and Richard R. Schrock were collectively awarded the 2005 Nobel Prize in Chemistry.

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更新时间:2025/6/20 18:54:30