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单词 Octahedral complex
释义

Octahedral complex

中文百科

八面体形分子构型 Octahedral molecular geometry

(重定向自Octahedral complex)
六氟化硫的结构为八面体形分子构型。

化学中,八面体形分子构型指的是一个分子中,中心原子上连有六个基团或配体而形成八面体的分子构型。理想的正八面体形分子属于Oh点群,例如六氟化硫SF6、六羰基钼Mo(CO)6等。使用“八面体”时比较随意,一般不考虑配体本身的形状,如[Co(NH3)6]在考虑N-H键时并不属于八面体,但仍称其为八面体型分子。

英语百科

Octahedral molecular geometry 八面体形分子构型

(重定向自Octahedral complex)
Structure of sulfur hexafluoride, an example of a molecule with the octahedral coordination geometry.

In chemistry, octahedral molecular geometry describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix octa. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh. Examples of octahedral compounds are sulfur hexafluoride SF6 and molybdenum hexacarbonyl Mo(CO)6. The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, [Co(NH3)6], which is not octahedral in the mathematical sense due to the orientation of the N-H bonds, is referred to as octahedral.

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更新时间:2025/6/21 6:48:10