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单词 Grignard Reagents
释义

Grignard Reagents

英语例句库

Abstract: One-pot synthesis method of diarylmethylamines was investigated using aryl lithium salt,thioformamide and aryl Grignard reagent.

摘 要: 由芳基锂盐、硫代甲酰胺和芳基格氏试剂一锅法合成了取代二芳基甲胺。

Synthesis of alkylated chlorosilane by Grignard reagent has been investigated,which provides a good way for preparation of organo-silicon compounds.

本文研究了用格氏法制备烷基取代氯硅烷的方法,为有机硅化合物的研制提供了一个较好的途径。

119.0 g of cyclopentyl bromide and 19.4 g of magnesium are reacted in ether or THF to give a cyclopentyl Grignard reagent.

119克环戊溴和19.4克镁在空气中或者四氢呋喃中加入环戊格林尼亚试剂作发生反应。

英语百科

Grignard reaction

A solution of a carbonyl compound is added to a Grignard reagent. (See gallery below)
Usually Grignard reagents are written as RMgX, but in fact the magnesium(II) centre is tetrahedral when dissolved in Lewis basic solvents, as shown here for the bis-adduct of methylmagnesium chloride and THF.

The Grignard reaction (pronounced /ɡriɲar/) is an organometallic chemical reaction in which alkyl, vinyl, or aryl-magnesium halides (Grignard reagents) add to a carbonyl group in an aldehyde or ketone. This reaction is an important tool for the formation of carbon–carbon bonds. The reaction of an organic halide with magnesium is not a Grignard reaction, but provides a Grignard reagent.

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更新时间:2025/6/21 3:46:15