Wien effect

The Wien effect is the experimentally-observed increase in ionic mobility or conductivity of electrolytes at very high gradient of electrical potential. A theoretical explanation has been proposed by Lars Onsager.

A related phenomenon is known as the Second Wien Effect or the dissociation field effect, and it involves increased dissociation constants of weak acids at high electrical gradients. The dissociation of weak chemical bases is unaffected.

单词	Dissociation field effect
释义	Dissociation field effect 英语百科 Wien effect The Wien effect is the experimentally-observed increase in ionic mobility or conductivity of electrolytes at very high gradient of electrical potential. A theoretical explanation has been proposed by Lars Onsager. A related phenomenon is known as the Second Wien Effect or the dissociation field effect, and it involves increased dissociation constants of weak acids at high electrical gradients. The dissociation of weak chemical bases is unaffected.
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Dissociation field effect

Wien effect