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单词 Diphosphoric acid
释义

Diphosphoric acid

中文百科

焦磷酸 Pyrophosphoric acid

(重定向自Diphosphoric acid)

焦磷酸,无色黏稠液体,久置生成结晶。由正磷酸失水而得。用水稀释可生成正磷酸。水溶液有强酸性。纯焦磷酸可由磷酸氢钠加热再将其溶解,转化成焦磷酸铅沉淀后通入硫化氢过滤,将滤液真空低温浓缩制得。

英语百科

Pyrophosphoric acid 焦磷酸

(重定向自Diphosphoric acid)

Pyrophosphoric acid, also known under the name diphosphoric acid, is colorless, odorless, hygroscopic and is soluble in water, diethyl ether, and ethyl alcohol. The anhydrous acid has two different forms, which melt at 54.3 °C and 71.5 °C. It is best prepared by ion exchange from sodium pyrophosphate or by reacting hydrogen sulfide with lead pyrophosphate. When phosphoric acid is dehydrated pyrophosphoric acid is produced as one of the products. When molten pyrophosphoric acid rapidly forms an equilibrium mixture of phosphoric acid, pyrophosphoric acid and polyphosphoric acids. The percentage by weight of pyrophosphoric acid is around 40% and it is difficult to recrystallise from the melt. In aqueous solution pyrophosphoric acid like all polyphosphoric acids hydrolyses and eventually an equilibrium is established between phosphoric acid pyrophosphoric acid and polyphosphoric acids. When highly diluted an aqueous solution of pyrophosphoric acid contains only phosphoric acid.

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更新时间:2025/6/19 22:35:42