| 单词 | Diels Alder reaction |
| 释义 |
Diels Alder reaction
原声例句
经济学人（汇总） Dr MacMillan came from the other end of the problem. He wanted to remove the metal (in this case copper) from the catalyst involved in a different process, the Diels–Alder reaction. 麦克米伦博士来自问题的另一端。他想从另一个过程——狄尔斯-阿尔德反应（Diels-Alder reaction）中的催化剂中去除金属（在这种情况下是铜）。 经济学人（汇总） Dr MacMillan found he could catalyse Diels-Alder reactions using a type of metal-free molecule called an imidazolidinone to activate the two-carbon component, meaning that it combines enthusiastically with its four-carbon compadre. 麦克米伦博士发现，他可以使用一种名为咪唑烷酮的无金属分子来催化狄尔斯-阿尔德反应，以激活双碳成分，这意味着它可以与其四碳化合物结合。
英语百科
Diels–Alder reaction    The Diels–Alder reaction is an organic chemical reaction (specifically, a [4+2] cycloaddition) between a conjugated diene and a substituted alkene, commonly termed the dienophile, to form a substituted cyclohexene system. It was first described by Otto Diels and Kurt Alder in 1928, for which work they were awarded the Nobel Prize in Chemistry in 1950. The Diels–Alder reaction is particularly useful in synthetic organic chemistry as a reliable method for forming 6-membered systems with good control over regio- and stereochemical properties. The underlying concept has also been applied to other π-systems, such as carbonyls and imines, to furnish the corresponding heterocycles, known as the hetero-Diels–Alder reaction. Diels–Alder reactions can be reversible under certain conditions; the reverse reaction is known as the retro-Diels–Alder reaction. |
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