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单词 demercuration
释义

demercuration

英汉-汉英词典
n. 脱汞(作用)
词组 | 习惯用语
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  • demonstration n. 示范;表达;实证;示威游行
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demercuration 脱汞

网络短语:
flue gas demercuration 烟气脱汞
中文百科

羟汞化反应 Oxymercuration reaction

(重定向自Demercuration)
羟汞化反应[1]
反应机理(顺序由上到下,电子转移用箭头标示)
羟汞化反应的区域选择性

羟汞化反应属于有机反应中的亲电加成反应,能把烯烃转换成饱和的醇类。在本反应中,烯烃和***(AcO–Hg–OAc)在水溶液中反应,双键两端分别接上***基团(HgOAc)与羟基(OH)。该反应不经历碳正离子中间体,为反式加成反应(两基团互为反式),且遵从马尔科夫尼科夫规则(羟基被加到较多个取代基的碳上)。 之后通常进行还原性的脱汞反应。两步反应合称羟汞化还原反应羟汞化脱汞反应

英语百科

Oxymercuration reaction 羟汞化反应

(重定向自Demercuration)
Oxymercuration reduction[1]
Curved-arrow mechanism, in sequential order from top to bottom.
Oxymercuration regioselectivity

The oxymercuration reaction is an electrophilic addition organic reaction that transforms an alkene into a neutral alcohol. In oxymercuration, the alkene reacts with mercuric acetate (AcO–Hg–OAc) in aqueous solution to yield the addition of an acetoxymercuri (HgOAc) group and a hydroxy (OH) group across the double bond. Carbocations are not formed in this process and thus rearrangements are not observed. The reaction follows Markovnikov's rule (the hydroxy group will always be added to the more substituted carbon) and it is an anti addition (the two groups will be trans to each other).

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更新时间:2025/6/19 7:25:30