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单词 Delocalized electron
释义

Delocalized electron

中文百科

离域电子

苯分子中的离域电子以图中圆圈表示。

离域电子英语:delocalized electron),也称游离电子,是在分子、离子或固体金属中不止与单一原子或单一共价键有关系的电子。 游离电子包含在分子轨道中,延伸到几个相邻的原子。一般来讲,离域电子存在于共轭系统和介离子化合物中。人们渐渐地了解到,σ键中的电子也会游离。例如甲烷中的成键电子是由五个原子共享的。更多细节详见分子轨道理论。

英语百科

Delocalized electron 离域电子

Benzene, with the delocalization of the electrons indicated by the circle.
Karotten

In chemistry, delocalized electrons are electrons in a molecule, ion or solid metal that are not associated with a single atom or a covalent bond. The term is general and can have slightly different meanings in different fields. In organic chemistry, this refers to resonance in conjugated systems and aromatic compounds. In solid-state physics, this refers to free electrons that facilitate electrical conduction. In quantum chemistry, this refers to molecular orbitals that extend over several adjacent atoms.

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更新时间:2025/6/20 1:50:05