Clathrochelate
![Structure of a clathrochelate complex, [Co(sepulchrate)]3+.](/uploads/202501/04/Clath22238.png)
In coordination chemistry, clathrochelates are ligands that encapsulate metal ions. Chelating ligands bind to metals more strongly than related monodentate ligands, and macrocyclic ligands bind more strongly than typical chelating ligands. It follows, that bi- or polymacrocyclic ligands would bind to metals particularly strongly. Clathrochelates are usually derived from bimacrocyclic ligands.