Ullage

Ullage or headspace is the unfilled space in a container, particularly with a liquid.
The word comes ultimately from the Latin oculus, “eye”, which was used in a figurative sense by the Romans for the bung hole of a barrel. This was taken into French in the medieval period as oeil, from which a verb ouiller was created, to fill a barrel up to the bung hole. In turn, a noun ouillage was created, which was the immediate source of the word's modern form, first recorded in Norman English about 1300, at first in the sense of the amount of liquid needed to fill a barrel up to the bung hole.