非整比化合物 Non-stoichiometric compound
非整比化合物(Non-stoichiometric compound,又译非化学计量化合物),又称贝多莱体(berthollides),指的是组成中各类原子的相对数目不能用几个小的整数比表示的化合物。
单词 | Berthollide compound |
释义 |
Berthollide compound
中文百科
非整比化合物 Non-stoichiometric compound(重定向自Berthollide compound)
非整比化合物(Non-stoichiometric compound,又译非化学计量化合物),又称贝多莱体(berthollides),指的是组成中各类原子的相对数目不能用几个小的整数比表示的化合物。
英语百科
Non-stoichiometric compound 非整比化合物(重定向自Berthollide compound)
![]() ![]() Non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having elemental composition whose proportions cannot be represented by integers; most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an otherwise perfect lattice work. Contrary to earlier definitions, modern understanding of non-stoichiometric compounds view them as homogenous, and not mixtures of stoichiometric chemical compounds. Since the solids are overall electrically neutral, the defect is compensated by a change in the charge of other atoms in the solid, either by changing their oxidation state, or by replacing them with atoms of different elements with a different charge. Many metal oxides and sulfides have non-stoichiometry examples; for example, stoichiometric iron(II) oxide, which is rare, has the formula FeO, whereas the more common material is nonstoichiometric, with the formula Fe0.95O. Non-stoichiometric compounds exhibit special electrical or chemical properties because of the defects; for example, when atoms are missing, the other atoms can move through the solid more rapidly. Non-stoichiometric compounds have applications in ceramic and superconductive material and in electrochemical (i.e., battery) system designs. |
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