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单词 berthollide
释义

berthollide /'bə:θə,laid/

英汉-汉英词典
n. 贝陀立体;非定比化合物;贝陀立合金
词组 | 习惯用语
您要查找的是不是:
  • Bertillon n. 贝迪永
  • Hollerith [计]利用凿孔把字母信息在卡片上编码的一种方式
  • Bartholdi 巴托尔迪
  • Bartholomew n. 巴塞洛缪

网络短语:
berthollide 贝多莱体
berthollide compound 伯托氏化合物
中文百科

非整比化合物 Non-stoichiometric compound

(重定向自Berthollide)

非整比化合物Non-stoichiometric compound,又译非化学计量化合物),又称贝多莱体berthollides),指的是组成中各类原子的相对数目不能用几个小的整数比表示的化合物。

英语百科

Non-stoichiometric compound 非整比化合物

(重定向自Berthollide)
Origin of title phenomena in crystallographic defects. Shown is a two-dimensional slice through a primitive cubic crystal system, showing the regular square array of atoms on one face (open circles, o), and with these, places where atoms are missing from a regular site to create vacancies, displaced to an adjacent acceptable space to create a Frenkel pair, or substituted by a smaller or larger atom not usually seen (closed circles, • ), in each case resulting in a material that is moved toward being measurably non-stoichiometric.
Pyrrhotite, an example of a non-stoichiometric inorganic compound, with formula Fe(1-x)S (x = 0 to 0.2).

Non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having elemental composition whose proportions cannot be represented by integers; most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an otherwise perfect lattice work. Contrary to earlier definitions, modern understanding of non-stoichiometric compounds view them as homogenous, and not mixtures of stoichiometric chemical compounds. Since the solids are overall electrically neutral, the defect is compensated by a change in the charge of other atoms in the solid, either by changing their oxidation state, or by replacing them with atoms of different elements with a different charge. Many metal oxides and sulfides have non-stoichiometry examples; for example, stoichiometric iron(II) oxide, which is rare, has the formula FeO, whereas the more common material is nonstoichiometric, with the formula Fe0.95O. Non-stoichiometric compounds exhibit special electrical or chemical properties because of the defects; for example, when atoms are missing, the other atoms can move through the solid more rapidly. Non-stoichiometric compounds have applications in ceramic and superconductive material and in electrochemical (i.e., battery) system designs.

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更新时间:2025/6/17 18:38:32