安息香缩合反应




安息香缩合反应,又称苯偶姻缩合,是一个有机反应,是氰离子(或硫胺素等噻唑衍生物)催化下两分子芳香醛进行缩合生成一个偶姻分子的反应。由于生成物是安息香(Ph-C(O)-CH(OH)-Ph)的衍生物,故名。
安息香缩合是羰基极性转换的一个典型例子。
单词 | Benzoin condensation |
释义 |
Benzoin condensation
中文百科
安息香缩合反应![]() ![]() ![]() ![]() 安息香缩合反应,又称苯偶姻缩合,是一个有机反应,是氰离子(或硫胺素等噻唑衍生物)催化下两分子芳香醛进行缩合生成一个偶姻分子的反应。由于生成物是安息香(Ph-C(O)-CH(OH)-Ph)的衍生物,故名。 安息香缩合是羰基极性转换的一个典型例子。
英语百科
Benzoin condensation 安息香缩合反应![]() ![]() ![]() ![]() The benzoin condensation is a reaction (often called a condensation reaction, for historical reasons) between two aromatic aldehydes, particularly benzaldehyde. The reaction is catalyzed by a nucleophile such as the cyanide anion or an N-heterocyclic carbene. The reaction product is an aromatic acyloin with benzoin as the parent compound. An early version of the reaction was developed in 1832 by Justus von Liebig and Friedrich Woehler during their research on bitter almond oil. The catalytic version of the reaction was developed by Nikolay Zinin in the late 1830s, and the reaction mechanism for this organic reaction was proposed in 1903 by A. J. Lapworth. |
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