Stereoselective oxidative dimerization of the enolate of carboxylic acid derivatives is summarized focusing on the stereoselectivity of the process.
综述羧酸衍生物的烯醇盐氧化二聚成键的规律,重点是立体选择性的过程。
单词 | Stereoselective |
释义 |
Stereoselective
英语例句库
Stereoselective oxidative dimerization of the enolate of carboxylic acid derivatives is summarized focusing on the stereoselectivity of the process. 综述羧酸衍生物的烯醇盐氧化二聚成键的规律,重点是立体选择性的过程。 In this thesis, the carbozincation of acetylenic sulfones and its applications in the stereoselective synthesis of polysubstituted olefins were investigated. 本论文研究了炔基砜的碳锌化反应及其原位产生的α-磺酰基烯基锌试剂在立体选择性合成多取代烯烃中的应用。
中文百科
立体选择性 Stereoselectivity(重定向自Stereoselective)
立体选择性,立体化学术语。 当一个反应生成A, B两个立体异构体,而A产量比B多的时候称相应的反应具有立体选择性。典型的立体选择性反应,比如有维蒂希反应,Horner-Wadsworth-Emmons反应,羟醛反应等等。
英语百科
Stereoselectivity 立体选择性(重定向自Stereoselective)
![]() ![]() ![]() ![]() In chemistry, stereoselectivity is the property of a chemical reaction in which a single reactant forms an unequal mixture of stereoisomers during the non-stereospecific creation of a new stereocenter or during the non-stereospecific transformation of a pre-existing one. The selectivity arises from differences in steric effects and electronic effects in the mechanistic pathways leading to the different products. Stereoselectivity can vary in degree but it can never be total since the activation energy difference between the two pathways is finite. However, in favorable cases, the minor stereoisomer may not be detectable by the analytic methods used. |
随便看 |
|
英汉网英语在线翻译词典收录了3779314条英语词汇在线翻译词条,基本涵盖了全部常用英语词汇的中英文双语翻译及用法,是英语学习的有利工具。