网站首页  英汉词典

请输入您要查询的英文单词:

 

单词 Sandmeyer reaction
释义

Sandmeyer reaction

中文百科

桑德迈尔反应

The Mechanism of the Sandmeyer Reaction

桑德迈尔反应Sandmeyer反应)是重氮盐在CuX的催化下与卤素盐类反应产生卤代烃的化学反应。

\rm \ R\!-\!N_2^++NaX \rightarrow R\!-\!X+N_2+Na^+

其中X可以为溴、氯或氰基负离子。

其机理如下(之前的重氮化反应略去):

英语百科

Sandmeyer reaction 桑德迈尔反应

The Mechanism of the Sandmeyer Reaction

The Sandmeyer reaction is a chemical reaction used to synthesize aryl halides from aryl diazonium salts. It is named after the Swiss chemist Traugott Sandmeyer. The reaction is a method for substitution of an aromatic amino group via preparation of its diazonium salt followed by its displacement with a nucleophile, often catalyzed by copper(I) salts. The nucleophile can include halide anions, cyanide, thiols, water, and others. The reaction does not proceed well with the fluoride anion, but fluorination can be carried out using tetrafluoroborate anions (Balz–Schiemann reaction).

随便看

 

英汉网英语在线翻译词典收录了3779314条英语词汇在线翻译词条,基本涵盖了全部常用英语词汇的中英文双语翻译及用法,是英语学习的有利工具。

 

Copyright © 2004-2024 encnc.com All Rights Reserved
更新时间:2025/6/19 17:06:14