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单词 Reaction rate constant
释义

Reaction rate constant

中文百科

速率常数

在化学动力学中,反应速率常数,又称速率常数 kλ是化学反应速率的量化表示方式。

对于反应物A反应物B反应成生成物C的化学反应,反应速率可表示成此式:

k(T)是反应速率常数,会随温度改变

[X]是假定反应发生处遍布于固定容积的溶液内,物质X的容积摩尔浓度。(当反应发生于一定范围,就能以X的单位面积摩尔数表示)

指数m和n称为反应级数,取决于反应机理。可由实验测定。

若为一次反应,亦可写成以下形式:

Ea是活化能,R是气体常数。因为温度T的分子能量可依波兹曼分布(en:Boltzmann distribution)求得,我们可预知能量大于Ea的碰撞比例随e变化,A 是指数前因子(en:Pre-exponential factor)或频率因子。

英语百科

Reaction rate constant 速率常数

In chemical kinetics a reaction rate constant or reaction rate coefficient, k, quantifies the rate of a chemical reaction.

For a reaction between reactants A and B to form product C

the reaction rate is often found to have the form:

Here k(T) is the reaction rate constant that depends on temperature. [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the solution. (For a reaction taking place at a boundary one would use instead moles of A or B per unit area).

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更新时间:2025/6/18 2:39:06