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单词 Rate Law
释义

Rate Law

原声例句
化学 Crash Course

A rate law in this form is said to be of the fourth order.

这种形式的速率定律被称为四阶速率定律。

化学 Crash Course

So in the rate law this can be expressed be the concentration being raised to the power of 1.

所以在速率定律中,这可以表示为浓度提高到 1 的次方。

化学 Crash Course

The exponents in rate laws are tricky even for professional chemists and engineers because like I said they can only be determined experimentally.

即使对于专业化学家和工程师来说,速率定律中的指数也很棘手,因为就像我说的那样,它们只能通过实验来确定。

化学 Crash Course

The rate law for a reaction is written like this: The rate equals a constant, k, times the concentrations of each reactant, raised to some power.

反应的速率定律是这样写的:速率等于常数 k 乘以每种反应物的浓度,提高到某个幂。

化学 Crash Course

The forward rate law if k multiplied by the concentration of A raised to some power times the initial concentration of B raised to some power.

如果 k 乘以 A 的某个幂的浓度乘以 B 的初始浓度的某个幂,则正向速率定律。

化学 Crash Course

The rate law for our nitric oxide reaction then ends up as k times the nitric oxide concentration raised to some power, times the hydrogen concentration also raised to some power.

然后,我们的一氧化氮反应的速率定律最终为 k 乘以一氧化氮浓度的某个幂,乘以氢气浓度的某个幂。

化学 Crash Course

So if we were to find the reverse rate law for a reaction it would take the same form as the forward one, but using the initial concentrations for the products rather than the reactants.

因此,如果我们要找到反应的反向速率定律,它将采用与正向速率相同的形式,但使用产物而不是反应物的初始浓度。

化学 Crash Course

This means that the final rate law for this reaction is: k times the concentration of hydrogen gas to the first power, you need to write out the 1 obviously, times the concentration of nitric oxide cubed.

这意味着这个反应的最终速率定律是:k乘以氢气浓度的一次方,显然你需要写出1乘以一氧化氮浓度的立方。

中文百科

速率方程 Rate equation

(重定向自Rate Law)
Concentration of A (A0 = 0.25 mole/l) and B versus time reaching equilibrium kf = 2 min−1 and kr = 1 min−1

化学反应速率方程是利用反应物浓度或分压计算化学反应的反应速率的方程。对于一个化学反应 mA + nB \rightarrow C\,,化学反应速率方程(与复杂反应速率方程相比较)的一般形式写作:

在这个方程中,[X]\, 表示一种给定的反应物 X\, 的活度,单位通常为摩尔每升(mol/L\,),但在实际计算中有时也用浓度代替(若该反应物为气体,表示分压,单位为帕斯卡 (Pa\,))。k\, 表示这一反应的速率常数,与温度、离子活度、光照、固体反应物的接触面积、反应活化能等因素有关,通常可通过阿累尼乌斯方程计算出来,也可通过实验测定。

指数x\,y\,为反应级数,取决于反应历程。在基元反应中,反应级数等于化学计量数。但在非基元反应中,反应级数与化学计量数不一定相等。

英语百科

Rate equation 速率方程

(重定向自Rate Law)
Concentration of A (A0 = 0.25 mole/l) and B versus time reaching equilibrium kf = 2 min−1 and kr = 1 min−1

The rate law or rate equation for a chemical reaction is an equation that links the reaction rate with concentrations or pressures of reactants and constant parameters (normally rate coefficients and partial reaction orders). For many reactions the rate is given by a power law such as

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更新时间:2025/6/24 3:42:12