应变 (化学) Strain (chemistry)




在化学的意义下,当一分子受到一应变影响,其化学结构对比于无应变的分子会受压力而产生内能。所有的能量保存于分子内的称为内能。一受应变的分子相对于不受应变的分子有着额外的内能。这些额外的内能或称为应变能,就如同压缩的弹簧。如同压缩的弹簧一般,必须保持紧压避免释放出势能,而分子可以不稳定的构型中维持内能是由于分子内的化学键,当这些化学键遭断键则势能就会瓦解。
单词 | Pitzer strain |
释义 |
Pitzer strain
中文百科
应变 (化学) Strain (chemistry)(重定向自Pitzer strain)
![]() ![]() ![]() ![]() 在化学的意义下,当一分子受到一应变影响,其化学结构对比于无应变的分子会受压力而产生内能。所有的能量保存于分子内的称为内能。一受应变的分子相对于不受应变的分子有着额外的内能。这些额外的内能或称为应变能,就如同压缩的弹簧。如同压缩的弹簧一般,必须保持紧压避免释放出势能,而分子可以不稳定的构型中维持内能是由于分子内的化学键,当这些化学键遭断键则势能就会瓦解。
英语百科
Strain (chemistry) 应变 (化学)(重定向自Pitzer strain)
![]() ![]() ![]() ![]() In chemistry, a molecule experiences strain when its chemical structure undergoes some stress which raises its internal energy in comparison to a strain-free reference compound. The internal energy of a molecule consists of all the energy stored within it. A strained molecule has an additional amount of internal energy which an unstrained molecule does not. This extra internal energy, or strain energy, can be likened to a compressed spring. Much like a compressed spring must be held in place to prevent release of its potential energy, a molecule can be held in an energetically unfavorable conformation by the bonds within that molecule. Without the bonds holding the conformation in place, the strain energy would be released. |
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