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单词 Pitzer strain
释义

Pitzer strain

中文百科

应变 (化学) Strain (chemistry)

(重定向自Pitzer strain)
例子:丁烷的对扭构象(anti)和间扭构象(gauche)
环己烷和甲基环戊烷
三烷基胺和三甲基硼的交互作用
烯丙基甲基和乙基团相当靠近

在化学的意义下,当一分子受到一应变影响,其化学结构对比于无应变的分子会受压力而产生内能。所有的能量保存于分子内的称为内能。一受应变的分子相对于不受应变的分子有着额外的内能。这些额外的内能或称为应变能,就如同压缩的弹簧。如同压缩的弹簧一般,必须保持紧压避免释放出势能,而分子可以不稳定的构型中维持内能是由于分子内的化学键,当这些化学键遭断键则势能就会瓦解。

英语百科

Strain (chemistry) 应变 (化学)

(重定向自Pitzer strain)
Examples of the anti and gauche conformations of butane.
Images of cyclohexane and methylcyclopentane.
Reaction of trialkylamines and trimethylboron.
Allylic methyl and ethyl groups are close together.

In chemistry, a molecule experiences strain when its chemical structure undergoes some stress which raises its internal energy in comparison to a strain-free reference compound. The internal energy of a molecule consists of all the energy stored within it. A strained molecule has an additional amount of internal energy which an unstrained molecule does not. This extra internal energy, or strain energy, can be likened to a compressed spring. Much like a compressed spring must be held in place to prevent release of its potential energy, a molecule can be held in an energetically unfavorable conformation by the bonds within that molecule. Without the bonds holding the conformation in place, the strain energy would be released.

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更新时间:2025/6/23 21:37:27