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单词 Order of reaction
释义

Order of reaction

英语例句库

Objective To explore the relationship between the illuminance and the observed order of reaction of photodegradation of nitrofurazone solution.

摘要目的研究呋喃西林水溶液光解反应的表观反应级数和光照度的关系。

中文百科

反应级数

反应级数,为化学反应速率方程中,反应物浓度的指数总和。

考虑一个假想的反应:

其反应速率(rate)为R,[A]与[B]代表反应物A跟B的浓度,k为速率常数(rate constant),则假设其速率方程可写成如下:

在上式中,m与n称为该反应物的反应分级数,或称作(部分级数(partial orders))。因此,反应对A是属于m级反应,对B而言为n级反应。而所有反应分级数的代数和称为反应级数,或称作(反应总级数(overall order)),在此例子也就代表反应总级数为m+n级。而上式中的m跟n或是m+n,也既是所谓的反应级数,除了可以是一级、二级、三级以外,还可以是零级、分数级或负数级甚至是无理数级,或是跟随反应条件(pH值、浓度)而变化,甚至速率方程中还可以出现反应产物的浓度项。

英语百科

Order of reaction 反应级数

In chemical kinetics, the order of reaction with respect to a given substance (such as reactant, catalyst or product) is defined as the index, or exponent, to which its concentration term in the rate equation is raised. For the typical rate equation of form r\; =\; k[\mathrm{A}]^x[\mathrm{B}]^y..., where [A], [B], ... are concentrations, the reaction orders (or partial reaction orders) are x for substance A, y for substance B, etc. The overall reaction order is the sum x + y + .... For many reactions, the reaction orders are not equal to the stoichiometric coefficients.

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更新时间:2025/6/18 1:10:35