阿伦尼乌斯方程 Arrhenius equation
zh-hans:阿伦尼乌斯方程 zh-hans:阿伦尼乌斯方程(或公式)是化学反应的速率常数与温度之间的关系式,适用于基元反应和非基元反应,甚至某些非均相反应。其不定积分形式为:
其中:
单词 | Arrhenius law |
释义 |
Arrhenius law
中文百科
阿伦尼乌斯方程 Arrhenius equation(重定向自Arrhenius law)
zh-hans:阿伦尼乌斯方程 zh-hans:阿伦尼乌斯方程(或公式)是化学反应的速率常数与温度之间的关系式,适用于基元反应和非基元反应,甚至某些非均相反应。其不定积分形式为: 其中:
英语百科
Arrhenius equation 阿伦尼乌斯方程(重定向自Arrhenius law)
The Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that Van 't Hoff's equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and reverse reactions. This equation has a vast and important application in determining rate of chemical reactions and for calculation of energy of activation . Arrhenius provided a physical justification and interpretation for the formula. Currently, it is best seen as an empirical relationship. It can be used to model the temperature variation of diffusion coefficients, population of crystal vacancies, creep rates, and many other thermally-induced processes/reactions. The Eyring equation, developed in 1935, also expresses the relationship between rate and energy. |
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