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单词 Lucas reagent
释义

Lucas reagent

中文百科

卢卡斯试剂 Lucas' reagent

(重定向自Lucas reagent)
卢卡斯试剂和乙醇无可见反应,和叔丁醇产生云雾状现象

卢卡斯试剂英语:Lucas' reagent)是无水氯化锌溶于高浓度盐酸所配制成的一种溶液。这种溶液被用于鉴别区分低分子量的醇。反应中氯会取代短链醇中的羟基,生成不溶于水的氯代烷,呈现沉淀。自从1930年被霍华德·卢卡斯报导以来,这个测试方法已经成为标准的鉴别方法。近年来这一方法已经被各种光谱和色谱分析方法所取代。

英语百科

Lucas' reagent 卢卡斯试剂

(重定向自Lucas reagent)
Lucas test: negative (left) with ethanol and positive with t-butanol

Lucas' reagent is a solution of anhydrous zinc chloride in concentrated hydrochloric acid. This solution is used to classify alcohols of low molecular weight. The reaction is a substitution in which the chloride replaces a hydroxyl group. A positive test is indicated by a change from clear and colourless to turbid, signalling formation of a chloroalkane. The test was reported in 1930 and became a standard method in qualitative organic chemistry. The test has since become somewhat obsolete with the availability of various spectroscopic and chromatographic methods of analysis. It was named after Howard Lucas (1885–1963), an American chemist.

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更新时间:2025/6/23 19:47:53