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单词 Ladderane
释义

Ladderane

中文百科

梯形烷

一种简单的梯形烷,其中包含三个稠合的四元环
Simple ladderane structure.
Ladderane Nomenclature
Cis vs. trans, syn vs. anti ladderanes

梯形烷(英文:ladderane),又称梯烷,是一种含有两个或多个稠合四元环的环烷烃。它的英文名ladderane是一个混成词,因为四元环的排列形状类似于梯子,并且是一种烷烃。有n个环的梯形烷化学式为C2n+2H2n+6。梯形烷的空间构型张力很大,因为碳原子上的配体不能使用正常的键角来成键。然而,梯形烷的例子已经在生物体内被发现。 一个典型的例子是五环厌氧氨氧化酸(Pentacycloanammoxic Acid), 它由五个稠合的环丁烷单元构成。它在细菌中进行厌氧氨氧化过程,这使得它形成了紧且厚的膜,这阻止了生物体失去肼中间体。后者参与了氮的产生和亚硝酸根离子与氨反应生成水。

英语百科

Ladderane 梯形烷

Simple ladderane structure.
Ladderane Nomenclature
Cis vs. trans, syn vs. anti ladderanes
Syntheses of ladderanes through cyclization

In chemistry, a ladderane is an organic molecule containing two or more fused cyclobutane rings. The name arises from the resemblance of a series of fused cyclobutane rings to a ladder. Numerous synthetic approaches have been developed for the synthesis of ladderane compounds of various lengths. The mechanisms often involve [2 + 2] photocycloadditions, a useful reaction for creating strained 4-membered rings. Naturally occurring ladderanes have been identified as major components of the anammoxosome membrane of the anammox bacteria, Planctomycetes.

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更新时间:2025/6/21 0:36:47