Isoaspartate

Isoaspartyl formation reaction of Asn-Gly (top right) to Asp-Gly (at left) or iso(Asp)-Gly (in green at bottom right).

The isoaspartate group is a functional group in biochemistry. Its formation is a chemical reaction in which the side chain of an asparagine or aspartic acid residue attacks the following peptide group (in black at top right of Figure 1), forming a symmetric succinimide intermediate (in red). The symmetry of the intermediate results in two products of its hydrolysis, either aspartate (in black at left) or in iso(Asp), which is a β-amino acid (in green at bottom right). The reaction also results in the deamidation of the asparagine residue.

单词	Isoaspartate
释义	Isoaspartate 英语百科 Isoaspartate The isoaspartate group is a functional group in biochemistry. Its formation is a chemical reaction in which the side chain of an asparagine or aspartic acid residue attacks the following peptide group (in black at top right of Figure 1), forming a symmetric succinimide intermediate (in red). The symmetry of the intermediate results in two products of its hydrolysis, either aspartate (in black at left) or in iso(Asp), which is a β-amino acid (in green at bottom right). The reaction also results in the deamidation of the asparagine residue.
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