同芳香性
同芳香性(英语:homoaromaticity)在有机化学中是指共平面的轮烯,它的π电子数为4n+2,共面的原子均为sp或sp杂化的轮烯上带有不与轮烯共面的取代基或桥。环辛四烯在浓硫酸中被质子化产生的C8H9是研究最多的同芳香性阳离子。
单词 | homoaromaticity |
释义 |
homoaromaticity
英汉-汉英词典
n. 同芳香性
词组 | 习惯用语
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网络短语:the homoaromaticity 同芳香性
英语例句库
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中文百科
同芳香性同芳香性(英语:homoaromaticity)在有机化学中是指共平面的轮烯,它的π电子数为4n+2,共面的原子均为sp或sp杂化的轮烯上带有不与轮烯共面的取代基或桥。环辛四烯在浓硫酸中被质子化产生的C8H9是研究最多的同芳香性阳离子。
英语百科
Homoaromaticity 同芳香性![]() ![]() ![]() ![]() Homoaromaticity, in organic chemistry, refers to a special case of aromaticity in which conjugation is interrupted by a single sp hybridized carbon atom. Although this sp center disrupts the continuous overlap of p-orbitals, traditionally thought to be a requirement for aromaticity, considerable thermodynamic stability and many of the spectroscopic, magnetic, and chemical properties associated with aromatic compounds are still observed for such compounds. This formal discontinuity is apparently bridged by p-orbital overlap, maintaining a contiguous cycle of π electrons that is responsible for this preserved chemical stability. |
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