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单词 homoaromaticity
释义

homoaromaticity

英汉-汉英词典
n. 同芳香性
词组 | 习惯用语
您要查找的是不是:
  • aromaticity n. 芳香性
  • monochromatic adj. 单色的、一色的
  • chromaticism n. 半音音阶之使用;富有半音音阶的音乐作风
  • arithmetician n. 算术家

网络短语:
the homoaromaticity 同芳香性
英语例句库
  1. Taking the example of the homoaromaticity of cyclooctriene cation and imidazole and oxazole basicity,the essay discusses the application of resonance theory.
    文中以环辛三烯正离子的同芳香性和咪唑与恶唑的碱性为例,讨论了共振论的应用。

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中文百科

同芳香性

同芳香性英语:homoaromaticity)在有机化学中是指共平面的轮烯,它的π电子数为4n+2,共面的原子均为sp或sp杂化的轮烯上带有不与轮烯共面的取代基或桥。环辛四烯在浓硫酸中被质子化产生的C8H9是研究最多的同芳香性阳离子。

英语百科

Homoaromaticity 同芳香性

Homoaromaticity, in organic chemistry, refers to a special case of aromaticity in which conjugation is interrupted by a single sp hybridized carbon atom. Although this sp center disrupts the continuous overlap of p-orbitals, traditionally thought to be a requirement for aromaticity, considerable thermodynamic stability and many of the spectroscopic, magnetic, and chemical properties associated with aromatic compounds are still observed for such compounds. This formal discontinuity is apparently bridged by p-orbital overlap, maintaining a contiguous cycle of π electrons that is responsible for this preserved chemical stability.

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更新时间:2025/6/23 2:43:41