Germanane

Germanane is a single-layer crystal composed of germanium with one hydrogen bonded in the z-direction for each atom. In material science, great interest is shown in related single layered materials, such as graphene, composed of carbon, and silicene, composed of silicon. Such materials represent a new generation of semiconductors with potential applications in computer chips and solar cells. Germanane’s structure is similar to graphane, and therefore graphene. Bulk germanium does not adopt this structure. Germanane has been produced in a two-step route starting with calcium germanide. From this material, the calcium is removed by de-intercalation with HCl to give a layered solid with the empirical formula GeH. The Ca sites in Zintyl-phase CaGe2 interchange with the H atoms in the HCl solution, which leaves us with GeH and CaCl2.