硫化铵
硫化铵,化学式为(NH4)2S。通常使用的是它的水溶液,固态不稳定,曝露在空气中会形成多硫化物和硫代硫酸盐。可用于摄影显色剂等。
硫化铵溶液,更准确地讲是硫氢化铵溶液,可由硫化氢通入氨水微热制得。浓氨水中通入硫化氢在常温下得到(NH4)2S·2NH4HS,0 °C再通入硫化氢则得到(NH4)2S·12NH4HS。用冰冷却,且不断通入硫化氢,会得到硫氢化铵溶液。
该溶液可溶解硫生成多硫化物铵盐: 2 (NH4)SH + ½ S8 ⇌ (NH4)2S4 + H2S
单词 | Ammonium sulfide |
释义 |
Ammonium sulfide
中文百科
硫化铵硫化铵,化学式为(NH4)2S。通常使用的是它的水溶液,固态不稳定,曝露在空气中会形成多硫化物和硫代硫酸盐。可用于摄影显色剂等。 硫化铵溶液,更准确地讲是硫氢化铵溶液,可由硫化氢通入氨水微热制得。浓氨水中通入硫化氢在常温下得到(NH4)2S·2NH4HS,0 °C再通入硫化氢则得到(NH4)2S·12NH4HS。用冰冷却,且不断通入硫化氢,会得到硫氢化铵溶液。 该溶液可溶解硫生成多硫化物铵盐: 2 (NH4)SH + ½ S8 ⇌ (NH4)2S4 + H2S
英语百科
Ammonium sulfide 硫化铵Ammonium sulfide, also known as diammonium sulfide, is an unstable salt with the formula (NH4)2S. Aqueous solutions purporting to contain this salt are commercially available. With a pKa exceeding 15, the hydrosulfide ion cannot be deprotonated to an appreciable amount by ammonia. Thus, such solutions mainly consist of a mixture of ammonia and (NH4)SH. Ammonium sulfide solutions are used occasionally in photographic developing, to apply patina to bronze, and in textile manufacturing. Also, due to its offensive smell, it is the active ingredient in a variety of foul pranks including the common stink bomb. |
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