内型-外型异构 Endo-exo isomerism


内型-外型异构(英语:Endo-exo isomerism)是指在桥环化合物之取代基形成的一种同分异构物。内型的异构物是指取代基离最长的桥最近或呈顺式的构型,外型的异构物是指取代基离最长的桥最远或呈反式的构型。此类的异构物可在降冰片烷接有取代基的化合物发现,右侧为示意图。在狄耳士–阿德尔反应(英语:Diels-Alder reactions)的立体选择性上也牵涉到此类异构物。
单词 | Exo isomer |
释义 |
Exo isomer
中文百科
内型-外型异构 Endo-exo isomerism(重定向自Exo isomer)
![]() ![]() 内型-外型异构(英语:Endo-exo isomerism)是指在桥环化合物之取代基形成的一种同分异构物。内型的异构物是指取代基离最长的桥最近或呈顺式的构型,外型的异构物是指取代基离最长的桥最远或呈反式的构型。此类的异构物可在降冰片烷接有取代基的化合物发现,右侧为示意图。在狄耳士–阿德尔反应(英语:Diels-Alder reactions)的立体选择性上也牵涉到此类异构物。
英语百科
Endo-exo isomerism 内型-外型异构(重定向自Exo isomer)
![]() ![]() Endo-exo isomerism is a special type of isomerism found in organic compounds with a substituent on a bridged ring system. The prefix endo is reserved for the isomer with the substituent located closest, or "syn", to the longest bridge. The prefix exo is reserved for the isomer with the substituent located farthest, or "anti", to the longest bridge. Here "longest" and "shortest" refer to the number of atoms that comprise the bridge. This type of molecular geometry is found in norbornane systems such as dicyclopentadiene. |
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