混合熵
设在一密闭容器的两边分别装有服从理想气体假设的两种气体1和2,其温度及压力均相同,中间以一隔板隔开。当隔板抽去之后,1 和2两种气体分别扩散至整个容器空间,直至分布均匀为止。设和
分别为气体1和气体2在混合气体中所占摩尔分数。混合熵
为:
其中为气体常数,
为气体的摩尔数。
单词 | Entropy of mixing |
释义 |
Entropy of mixing
中文百科
混合熵设在一密闭容器的两边分别装有服从理想气体假设的两种气体1和2,其温度及压力均相同,中间以一隔板隔开。当隔板抽去之后,1 和2两种气体分别扩散至整个容器空间,直至分布均匀为止。设 其中
英语百科
Entropy of mixing 混合熵In thermodynamics the entropy of mixing is the increase in the total entropy when several initially separate systems of different composition, each in a thermodynamic state of internal equilibrium, are mixed without chemical reaction by the thermodynamic operation of removal of impermeable partition(s) between them, followed by a time for establishment of a new thermodynamic state of internal equilibrium in the new unpartitioned closed system. |
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