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单词 allylation
释义

allylation

英汉-汉英词典
烯丙基化(作用)
词组 | 习惯用语
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  • installation n. 安装;装置;军事驻地
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  • titillation n. 搔痒;愉快
allylation n. 烯丙基化,烯丙基化作用

网络短语:
carbonyl allylation 羰基烯丙基化
allylation reaction 烯丙基化反应
asymmetric allylation 不对称烯丙基化反应
selective allylation 选择性加成反应
allylation reactions 烯丙基化反应
Brown asymmetric allylation Brown不对称烯丙基化
aqueous allylation reaction 水相中的烯丙基化反应
英语百科

Allyl

Structure of the allyl group.
The free radical pathway for the first phase of the oxidative rancidification of fats.
A representative triglyceride found in linseed oil features groups with both singly and doubly allylic CH2 sites (linoleic acid and alpha-linolenic acid) and singly allylic sites (oleic acid).
MO diagram for pi-orbitals on the allyl radical.  The middle MO labeled Ψ2 is singly occupied in the allyl radical.  In the allyl cation Ψ2 is unoccupied and in the allyl anion it is doubly occupied.  Hydrogen atoms are omitted from this picture.

An allyl group is a substituent with the structural formula H2C=CH-CH2R, where R is the rest of the molecule. It consists of a methylene bridge (-CH2-) attached to a vinyl group (-CH=CH2). The name is derived from the Latin word for garlic, Allium sativum. In 1844, Theodor Wertheim isolated an allyl derivative from garlic oil and named it "Schwefelallyl". The term allyl applies to many compounds related to H2C=CH-CH2, some of which are of practical or of everyday importance for example allyl chloride.

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更新时间:2025/6/20 21:02:27