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单词 alkylidene
释义

alkylidene

英汉-汉英词典
n. 亚烷基;烷叉
词组 | 习惯用语
您要查找的是不是:
  • identical adj. 同一的
  • alkaline adj. [化]碱性的,碱的
  • alkaloid n. 生物碱;植物碱基
  • alkalinity n. 碱度
alkylidene n. 烷叉

网络短语:
alkylidene malonate 亚烷基丙二酸二脂
alkylidene-H 烷叉
alkylidene radica 烷叉基
alkylidene radical 亚烷基;翻译;烷叉基
alkylidene complexes 烃叉络合物
alkylidene bisphenol 次烷基双酚
alkylidene barbituric acid 亚烃基巴比妥酸
Isopropylidene alkylidene malonates 亚烃基丙二酸亚异丙酯
5 alkylidene barbituric acid 亚烃基巴比妥酸
中文百科

过渡金属卡宾配合物 Transition metal carbene complex

(重定向自Alkylidene)

过渡金属卡宾配合物可用通式LnM=CR2表示,它在形式上含有M=C双键。自由状态的卡宾:CR2由于碳原子的形式氧化态为+2价,碳原子周围只有6个价电子因而异常活泼,寿命极短,它们是许多有机化学反应的中间体,仅有少数几例可以分离得到。虽然卡宾不能直接和金属反应,但卡宾能和金属结合形成配合物而稳定。

英语百科

Transition metal carbene complex 过渡金属卡宾配合物

(重定向自Alkylidene)
The first metal carbene complex, Chugaev's red salt, was not recognized as such until decades after its preparation.[4]

A transition metal carbene complex is an organometallic compound featuring a divalent organic ligand. The divalent organic ligand coordinated to the metal center is called a carbene. Carbene complexes for almost all transition metals have been reported. Many methods for synthesizing them and reactions utilizing them have been reported. The term carbene ligand is a formalism since many are not derived from carbenes and almost none exhibit the reactivity characteristic of carbenes. Described often as M=CR2, they represent a class of organic ligands intermediate between alkyls (−CR3) and carbynes (≡CR). They feature in some catalytic reactions, especially alkene metathesis, and are of value in the preparation of some fine chemicals.

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更新时间:2025/6/18 7:00:42