过渡金属卡宾配合物 Transition metal carbene complex

过渡金属卡宾配合物可用通式LnM=CR2表示,它在形式上含有M=C双键。自由状态的卡宾:CR2由于碳原子的形式氧化态为+2价,碳原子周围只有6个价电子因而异常活泼,寿命极短,它们是许多有机化学反应的中间体,仅有少数几例可以分离得到。虽然卡宾不能直接和金属反应,但卡宾能和金属结合形成配合物而稳定。
单词 | alkylidene |
释义 |
alkylidene
英汉-汉英词典
n. 亚烷基;烷叉
词组 | 习惯用语
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alkylidene n. 烷叉 网络短语:alkylidene malonate 亚烷基丙二酸二脂 alkylidene-H 烷叉 alkylidene radica 烷叉基 alkylidene radical 亚烷基;翻译;烷叉基 alkylidene complexes 烃叉络合物 alkylidene bisphenol 次烷基双酚 alkylidene barbituric acid 亚烃基巴比妥酸 Isopropylidene alkylidene malonates 亚烃基丙二酸亚异丙酯 5 alkylidene barbituric acid 亚烃基巴比妥酸
中文百科
过渡金属卡宾配合物 Transition metal carbene complex(重定向自Alkylidene)
![]() 过渡金属卡宾配合物可用通式LnM=CR2表示,它在形式上含有M=C双键。自由状态的卡宾:CR2由于碳原子的形式氧化态为+2价,碳原子周围只有6个价电子因而异常活泼,寿命极短,它们是许多有机化学反应的中间体,仅有少数几例可以分离得到。虽然卡宾不能直接和金属反应,但卡宾能和金属结合形成配合物而稳定。
英语百科
Transition metal carbene complex 过渡金属卡宾配合物(重定向自Alkylidene)
![]() ![]() A transition metal carbene complex is an organometallic compound featuring a divalent organic ligand. The divalent organic ligand coordinated to the metal center is called a carbene. Carbene complexes for almost all transition metals have been reported. Many methods for synthesizing them and reactions utilizing them have been reported. The term carbene ligand is a formalism since many are not derived from carbenes and almost none exhibit the reactivity characteristic of carbenes. Described often as M=CR2, they represent a class of organic ligands intermediate between alkyls (−CR3) and carbynes (≡CR). They feature in some catalytic reactions, especially alkene metathesis, and are of value in the preparation of some fine chemicals. |
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